Vol 5 Issue 3

A graphene toaster was demonstrated for the first time at the consumer electronics show in Las Vegas by Korean company Graphene Square. This may not sound like a world changing invention, but it is something worth paying attention to because this is a rare application for chemical vapour deposition (CVD) graphene in a consumer electronics device. Until now, CVD graphene has been used in very small pieces in sensors. This toaster has a piece of CVD graphene on the top and bottom glass panels making a transparent infrared grill. The graphene is made at a scale of 200mm x 150mm and this tells us a that the company has a viable CVD roll to roll process. The process can make graphene at this scale and also provides the capability to separate the graphene from the forming substrate to other surfaces, in this case glass. The next step is to do this commercially. Graphene Square admits this is still at least a year away. This is still impressive progress and tells us that the industrial manufacture of CVD graphene is developing quickly. CVD graphene is also in the news this month. British company Paragraf announced through Queen Mary University, London, that they can create graphene at wafer scale, and this could be a replacement for indium tin oxide (ITO). This was picked up by technology blogs around the world, and graphene manufacturer Versarien felt obliged to disclose it is working on a similar project with a graphene manufacturer in Korea. These announcements about CVD graphene touchscreens sound impressive. However, as far as we can tell from the current state of the art, the economic and technical cases are not sufficiently proven to convince us we will see this technology in the immediate future. The term ‘bottom-up graphene’ used to refer to CVD graphene assembled atom by atom. Graphene powder manufacturing has been evolving rapidly over the last few years and can now be made by atomic assembly methods too. We have summarised the various methods in our special feature. We also look at the implications for competitive activity, as these new manufacturing methods meet the new market dynamics driving the sustainability agenda. While we cannot state which individual companies will achieve success, we can make some predictions about the characteristics successful graphene powder manufacturers will need to have. We hope you agree this makes for fascinating reading along with the rest of the compelling content this issue. Adrian Nixon, 1st February 2022

Evidence is mounting in support of the low toxicity of graphene. The Swiss federal research laboratories have added to the body of evidence this month (p.16). They explored the effects of dusts generated by graphene enhanced polymers when they are abraded and found no toxic effects and minor respiratory inflammation. This means the dusts created during the recycling process of graphene enhanced polymer composites (in this case, nylon PA6) represent a low health hazard. As a regular reader, you will know that graphene is being trialled as an additive to enhance the life of asphalt roads. In the UK Kent County Council and the University of Nottingham have just released data from the field trials on roads in the county (p.33). They found that graphene: • Extends the surface lifetime by approximately 2.5 times to last up to 25 years • Over 65-year asset life, a carbon saving of 23kg CO2/m2 of road surface • Created a 32% reduction in cost over the lifetime of the asset Graphene applications supported by data get more of our attention. GMG has commissioned its graphene enhanced battery plant in Australia. These batteries have a lower energy density than lithium ion and nickel metal batteries. This might not sound important, but aluminium and graphene are common materials that can be made with low environmental impact when compared with lithium, cobalt & nickel. A new electric vehicle has been launched this month. UK hypercar manufacturer has presented its Apricale hydrogen fuel cell electric vehicle (HFCEV). The car has a top speed of over 300km/hr and a range over 500km. Graphene enhanced polymer composites are used to make the hydrogen fuel tank. The car does need batteries but because these are for supporting power it needs much less than a normal EV. This raises an interesting possibility, could lower energy density battery technology such as aluminium ion be used in conjunction with fuel cell technology to make better, sustainable electric vehicles? All these developments use graphene powders. Meanwhile large area sheet CVD graphene makes steady progress. A team at the University of Texas has made a ‘graphene tattoo’ sensor that can be applied to the skin to continuously monitor blood pressure. Using graphene means there is no inflammatory response from the wearer, and the sensor provides the highest sensitivity rating. Continuing the CVD theme, we interview the CEO of one of the leading graphene manufacturing companies, Jeff Draa provides insight into how he makes his CVD graphene and how they monitored customers to help them focus on the applications most likely to drive commercial success. You can find out about all this and more in this fascinating issue, dear reader please read on… Adrian Nixon 1st July 2022